A single particle model with electrolyte and side reactions for degradation of lithium-ion batteries

DOI10.1016/J.APM.2022.12.009MaRDI QIDQ6072783zbMATH OpenOpenAlexFDO

Authors Ferran Brosa Planella, W. Dhammika Widanage

Publication date 13 October 2023

Published in Applied Mathematical Modelling (Search for Journal in Brave)

Copyright license Creative Commons Attribution 4.0 International

Full work available at URL https://arxiv.org/abs/2206.05078

zbMATH Keywords

asymptotic methodslithium platinglithium-ion batteriesmodel reductionsingle particle modelsolid-electrolyte interphase growth

Mathematics Subject Classification ID

Electrochemistry (78A57)

Abstract: Battery degradation, which is the reduction of performance over time, is one of the main roadblocks to the wide deployment of lithium-ion batteries. Physics-based models, such as those based on the Doyle-Fuller-Newman model, are invaluable tools to understand and predict such phenomena. However, these models are often too complex for practical applications, so reduced models are needed. In this article we introduce the Single Particle Model with electrolyte and Side Reactions, a reduced model with electrochemical degradation which has been formally derived from the Doyle-Fuller-Newman model with Side Reactions using asymptotic methods. The reduced model has been validated against the full model for three scenarios (solid-electrolyte interphase growth, lithium plating, and both effects combined) showing similar accuracy at a much lower computational cost. The implications of the results are twofold: the reduced model is simple and accurate enough to be used in most real practical applications, and the reduction framework used is robust so it can be extended to account for further degradation effects.

Cites work

• Asymptotic reduction of a porous electrode model for lithium-ion batteries
• CasADi: a software framework for nonlinear optimization and optimal control
• Finite Volume Methods for Hyperbolic Problems
• scientific article; zbMATH DE number 49093 (Why is no real title available?)
• scientific article; zbMATH DE number 1409619 (Why is no real title available?)
• Method of lines PDE analysis in biomedical science and engineering
• SUNDIALS

Cited in

(4)

• On the significance of sulphuric acid dissociation in the modelling of Vanadium redox flow batteries
• A thermo-chemo-mechanically coupled model for cathode particles in lithium-ion batteries
• Phase-field study of electrochemical reactions at exterior and interior interfaces in Li-ion battery electrode particles
• Deterministic and stochastic analysis of the lithiation/delithiation dynamics of a cathode nanoparticle

This page was built for publication: A single particle model with electrolyte and side reactions for degradation of lithium-ion batteries

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q6072783)