Chemical systems with limit cycles

DOI10.1007/S11538-023-01170-3zbMATH Open1519.92363arXiv2211.05755OpenAlexW4383058277MaRDI QIDQ6168043FDOQ6168043

Radek Erban, Hye-Won Kang

Publication date: 8 August 2023

Published in: Bulletin of Mathematical Biology (Search for Journal in Brave)

Abstract: The dynamics of a chemical reaction network (CRN) is often modelled under the assumption of mass action kinetics by a system of ordinary differential equations (ODEs) with polynomial right-hand sides that describe the time evolution of concentrations of chemical species involved. Given an arbitrarily large integer $KinmathbbN$, we show that there exists a CRN such that its ODE model has at least $K$ stable limit cycles. Such a CRN can be constructed with reactions of at most second order provided that the number of chemical species grows linearly with $K$. Bounds on the minimal number of chemical species and the minimal number of chemical reactions are presented for CRNs with $K$ stable limit cycles and at most second order or seventh order kinetics. We also show that CRNs with only two chemical species can have $K$ stable limit cycles, when the order of chemical reactions grows linearly with $K$.

Full work available at URL: https://arxiv.org/abs/2211.05755

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zbMATH Keywords

chemical reaction networkslimit cyclesmass action kinetics

Mathematics Subject Classification ID

Topological structure of integral curves, singular points, limit cycles of ordinary differential equations (34C05) Classical flows, reactions, etc. in chemistry (92E20)

Cites Work

• Title not available (Why is that?)
• Systems of Differential Equations Which Are Competitive or Cooperative: I. Limit Sets
• Existence of periodic orbits for high-dimensional autonomous systems
• Centennial History of Hilbert's 16th Problem
• Nonlinear dynamics and chaos. With applications to physics, biology, chemistry, and engineering
• Title not available (Why is that?)
• Universal formats for nonlinear ordinary differential systems
• Title not available (Why is that?)
• A cubic system with thirteen limit cycles
• EXISTENCE CONDITIONS OF THIRTEEN LIMIT CYCLES IN A CUBIC SYSTEM
• Phase asymptotic semiflows, Poincaré's condition, and the existence of stable limit cycles
• Stochastic Modelling of Reaction–Diffusion Processes
• No limit cycle in two species second order kinetics.
• Chemical reaction systems with a homoclinic bifurcation: an inverse problem
• Chemical systems consisting only of elementary steps -- a paradigma for nonlinear behavior
• Realizations of kinetic differential equations
• Test Models for Statistical Inference: Two-Dimensional Reaction Systems Displaying Limit Cycle Bifurcations and Bistability
• Limit cycles in mass-conserving deficiency-one mass-action systems

Cited In (7)

• Prevalence of Multistationarity and Absolute Concentration Robustness in Reaction Networks
• Title not available (Why is that?)
• Isochronicity and limit cycle oscillation in chemical systems
• On the relation between \(\omega \)-limit set and boundaries of mass-action chemical reaction networks
• Title not available (Why is that?)
• Rigorously proven chaos in chemical kinetics
• A calculus of chemical systems

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