Nonequilibrium thermodynamics at the microscale: work relations and the second law

DOI10.1016/J.PHYSA.2010.01.001MaRDI QIDQ647829zbMATH OpenOpenAlexWikidataFDO

Authors Eliran Boksenbojm, Bram Wynants, Christopher Jarzynski

Publication date 19 November 2011

Published in Physica A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1002.1230

Mathematics Subject Classification ID

Irreversible thermodynamics, including Onsager-Machlup theory (82C35)

Abstract: For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this result must be considered statistically, as fluctuations around average behavior become substantial. In recent years it has become recognized that these fluctuations satisfy a number of strong and unexpected relations, which remain valid even when the system is driven far from equilibrium. We discuss these relations, and consider what they reveal about the second law of thermodynamics and the nature of irreversibility at the microscale.

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Cites work

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• Nonequilibrium measurements of free energy differences for microscopically reversible Markovian systems
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• Probability of second law violations in shearing steady states
• The fluctuation theorem as a Gibbs property
• Time-reversal and entropy

Cited in

(18)

• The second law of thermodynamics at the microscopic scale
• Is thermodynamic irreversibility a consequence of the expansion of the universe?
• Jarzynski equality for superconducting optical cavities: an alternative path to determine Helmholtz free energy
• Escapement mechanisms and the conversion of disequilibria; \textit{the engines of creation}
• Second law of thermodynamics for macroscopic mechanics coupled to thermodynamic degrees of freedom
• Insights into the second law of thermodynamics from anisotropic gas-surface interactions
• About some current frontiers of the second law
• A note on the Jarzynski equality
• Nonequilibrium work relation in a macroscopic system
• Work fluctuation, second law and free-energy recovery methods: perspectives in theory and experiments
• scientific article; zbMATH DE number 2069976 (Why is no real title available?)
• scientific article; zbMATH DE number 2183261 (Why is no real title available?)
• Introducing one-shot work into fluctuation relations
• Statistics of work and fluctuation theorems for microcanonical initial states
• Microscopic foundation of the second law of thermodynamics within nonunitary Newtonian gravity
• The second law for small systems
• Work-Hamiltonian connection for anisoparametric processes in manipulated microsystems
• Nonequilibrium work relations: foundations and applications

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