Phase space reaction dynamics associated with an index-2 saddle point for time-dependent Hamiltonian systems

DOI10.1142/S0218127422300361MaRDI QIDQ6537564zbMATH OpenFDO

Authors Hengchang Cao, Stephen Wiggins

Publication date 14 May 2024

Published in International Journal of Bifurcation and Chaos in Applied Sciences and Engineering (Search for Journal in Brave)

zbMATH Keywords

time-dependent Hamiltoniantime-dependent phase space structuretime-dependent reaction dynamicsindex-2 saddle points

Mathematics Subject Classification ID

Stability problems for finite-dimensional Hamiltonian and Lagrangian systems (37J25) Equilibria and periodic trajectories for nonlinear problems in mechanics (70K42) Stability for nonlinear problems in mechanics (70K20)

Cites work

• Classical and quantum dynamical manifestations of index-\(2\) saddles: concerted versus sequential reaction mechanisms
• Direct construction of a dividing surface of minimal flux for multi-degree-of-freedom systems that cannot be recrossed
• Exploring isomerization dynamics on a potential energy surface with an index-2 saddle using Lagrangian descriptors
• Influence of low frequency modes on dynamical concertedness in double proton transfer dynamics
• Phase-space geometry and reaction dynamics near index 2 saddles
• Second-order saddle dynamics in isomerization reaction
• The geometry of reaction dynamics
• The role of normally hyperbolic invariant manifolds (NHIMS) in the context of the phase space setting for chemical reaction dynamics
• The role of time-dependent phase space structures in reaction dynamics and the no-recrossing property of dividing surfaces
• Transition state geometry near higher-rank saddles in phase space
• Wigner's dynamical transition state theory in phase space: classical and quantum

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