Structural isomers, double wells, resonances, and Dirichlet decoupling

DOI10.1016/0003-4916(84)90051-4MaRDI QIDQ760584zbMATH OpenOpenAlexFDO

Authors E. Brian Davies

Publication date 1984

Published in Annals of Physics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1016/0003-4916(84)90051-4

zbMATH Keywords

Dirichlet boundary conditionDirichlet decouplingdouble wellsfunctional integrationresonancesSchrödinger operatorsstructural isomers

Mathematics Subject Classification ID

Schrödinger operator, Schrödinger equation (35J10) Functional calculus for linear operators (47A60) Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05)

Review text

An operator \(H=-\Delta +V\) is replaced by K which is obtained from H by imposing a Dirichlet boundary condition on some bounded surface S. S partitions \(R^ n\) into \(n+1\) subregions, n being a number of minima of a potential V. It is proven that \(Tr(e^{-Ht}-e^{-Kt}),\) \(\| e^{- Ht}-e^{-Kt}\|\) and \(\| (H+\lambda)^{-m}-(K+\lambda)^{- m}\|\) are small, with bounds being obtained by functional integration.

Recommendations

• Double Well Hamiltonians
• On Dirichlet-Schrödinger operators with strong potentials
• Publication:4892708
• scientific article; zbMATH DE number 3994146
• scientific article; zbMATH DE number 4067681

Cites work

• An adiabatic theorem applicable to the Stark effect
• Convergent expansions for tunneling
• Double wells
• scientific article; zbMATH DE number 4040647 (Why is no real title available?)
• scientific article; zbMATH DE number 3676222 (Why is no real title available?)
• scientific article; zbMATH DE number 3776371 (Why is no real title available?)
• HYPERCONTRACTIVE AND RELATED BOUNDS FOR DOUBLE WELL SCHRÖDINGER HAMILTONIANS
• Krein's formula and one-dimensional multiple-well
• Metastable States of Symmetric Markov Semigroups II
• New approach to the semiclassical limit of quantum mechanics. I: Multiple tunnelings in one dimension
• On the rate of asymptotic eigenvalue degeneracy
• Perturbation theory for shape resonances and large barrier potentials
• Resonances in n-body quantum systems with dilatation analytic potentials and the foundations of time-dependent perturbation theory
• Schrödinger semigroups
• Spectral properties of many-body Schrödinger operators with dilatation- analytic interactions
• Spectral properties of metastable Markov semigroups
• The mathematical theory of resonances whose widths are exponentially small
• THE RATE OF RESOLVENT AND SEMIGROUP CONVERGENCE

Cited in

(6)

• Universal lower bounds on eigenvalue splittings for one dimensional Schrödinger operators
• scientific article; zbMATH DE number 4163585 (Why is no real title available?)
• Vibrational isotope effect by the low rank perturbation method
• Editors' introduction
• Solution of a mountain pass problem for the isomerization of a molecule with one free atom
• Vibrational isotope effect by the low rank perturbation method. Case study: out-of-plane vibrations of benzene (H,D)-isotopomers

This page was built for publication: Structural isomers, double wells, resonances, and Dirichlet decoupling

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q760584)