force constant (anharmonic)

Community: MathModDB

quantity

Available identifiers

MaRDI QIDQ6673744

coefficients of the nth (n>=3) order term in a Taylor expansion of the potential energy wrt displacements from a minimum energy configuration

Description

Cubic, quartic, ... anharmonic force constants are the coefficients of the third, fourth, ... order term in a Taylor expansion of the potential energy wrt displacements from a minimum energy configuration.

Quantities specializing force constant (anharmonic)

spring constant

Related URL

https://en.wikipedia.org/wiki/Anharmonicity
https://www.wikidata.org/wiki/Q545228

Further items linking to force constant (anharmonic)

Item	Property
anharmonicity constant (perturbation theory)	symbol represents
quantum Hamiltonian (normal mode, anharmonic)	symbol represents
quantum Hamiltonian (normal mode, intermolecular)	symbol represents
vibrational frequency shift (2nd order)	symbol represents

This page was built for quantity: force constant (anharmonic)