Thermal ionization

DOI10.1023/B:MPAG.0000034613.13746.8AMaRDI QIDQ702508zbMATH OpenFDO

Authors Jürg Fröhlich, M. Merkli

Publication date 17 January 2005

Published in Mathematical Physics, Analysis and Geometry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/math-ph/0410010

zbMATH Keywords

black-body radiationCCR algebraFermi Golden RuleLiouville operatorMourré estimateopen quantum systempositive commutatorsstandard form of von Neumann algebrasvirial theorem

Mathematics Subject Classification ID

Noncommutative dynamical systems (46L55) Applications of selfadjoint operator algebras to physics (46L60) Applications of functional analysis in quantum physics (46N50) Quantum dynamics and nonequilibrium statistical mechanics (general) (82C10)

Abstract: In the context of an idealized model describing an atom coupled to black-body radiation at a sufficiently high positive temperature, we show that the atom will end up being ionized in the limit of large times. Mathematically, this is translated into the statement that the coupled system does not have any time-translation invariant state of positive (asymptotic) temperature, and that the expectation value of an arbitrary finite-dimensional projection in an arbitrary initial state of positive (asymptotic) temperature tends to zero, as time tends to infinity. These results are formulated within the general framework of $W^{\ast }$-dynamical systems, and the proofs are based on Mourre's theory of positive commutators and a new virial theorem. Results on the so-called standard form of a von Neumann algebra play an important role in our analysis.

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Cited in

(22)

• Ergodicity of the spin-boson model for arbitrary coupling strength
• Quantum Markovian master equations: resonance theory shows validity for all time scales
• Ionization of atoms in a thermal field
• Stability of equilibria with a condensate
• Thermal ionization for short-range potentials
• Correlation decay and Markovianity in open systems
• The preparation of states in quantum mechanics
• Fully coupled Pauli-Fierz systems at zero and positive temperature
• Representations of canonical commutation relations describing infinite coherent states
• Quantum electron transport in degenerate donor-acceptor systems
• Stability of Multi-Phase Equilibria
• Random phase infinite coherent states: Construction and dynamics
• An infinite level atom coupled to a heat bath
• The thermalization process of an atom with the thermal radiation field
• On the atomic photoeffect in non-relativistic QED
• Qualitative model of the hydrogen peroxide positive ion in a heat bath
• On the thermodynamic limit of interacting fermions in the continuum
• Disjointness of inertial KMS states and the role of Lorentz symmetry in thermalization
• Another return of ``Return to equilibrium
• Level shift operators for open quantum systems
• Instability of equilibrium states for coupled heat reservoirs at different temperatures
• Status of the fundamental laws of thermodynamics

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