Transient fluctuation theorems for the currents and initial equilibrium ensembles
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Abstract: We prove a transient fluctuation theorem for the currents for continuous-time Markov jump processes with stationary rates, generalizing an asymptotic result by Andrieux and Gaspard [J. Stat. Phys. 127, 107 (2007)] to finite times. The result is based on a graph theoretical decomposition in cycle currents and an additional set of tidal currents that characterize the transient relaxation regime. The tidal term can then be removed by a preferred choice of a suitable initial equilibrium ensemble, a result that provides the general theory for the fluctuation theorem without ensemble quantities recently addressed in [Phys. Rev. E 89, 052119 (2014)]. As an example we study the reaction network of a simple stochastic chemical engine, and finally we digress on general properties of fluctuation relations for more complex chemical reaction networks.
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Cites work
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Cited in
(14)- On the asymptotic convergence of the transient and steady-state fluctuation theorems
- Effective fluctuation and response theory
- Affinity- and topology-dependent bound on current fluctuations
- Multivariable fluctuation theorems in the steady-state cycle kinetics of single enzyme with competing substrates
- The measure-theoretic identity underlying transient fluctuation theorems
- Fluctuation theorem for birth–death or chemical master equations with time-dependent rates
- Lag inequality for birth–death processes with time-dependent rates
- Cycle/cocycle oblique projections on oriented graphs
- A fluctuation theorem for currents and non-linear response coefficients
- The fluctuation theorem for currents in semi-Markov processes
- The transient fluctuation theorem of sample entropy production for general stochastic processes
- Fluctuation relations for a few observable currents at their own beat
- Effective affinity for generic currents in Markov processes
- Fluctuation theorem for currents and Schnakenberg network theory
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