Volume changes in glassy polymers

DOI10.1007/S004190050197MaRDI QIDQ1291892zbMATH OpenOpenAlexFDO

Authors Aleksey D. Drozdov

Publication date 25 July 2001

Published in Archive of Applied Mechanics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1007/s004190050197

zbMATH Keywords

compressible glassy polymersfinite strainsnon-isothermal loadingPoisson ratiostress-strain relationstime-dependent Young modulusuniaxial extensionviscoelastic barviscoelasticityvolume relaxation

Mathematics Subject Classification ID

Theory of constitutive functions in solid mechanics (74A20) Nonlinear constitutive equations for materials with memory (74D10) Statistical mechanics of polymers (82D60)

Review text

The author derives constitutive relations for compressible glassy polymers with finite strains under non-isothermal loading. The stress-strain relations are applied to the analysis of uniaxial extension of a viscoelastic bar. Explicit formulae are developed for the time-dependent Young modulus and Poisson ratio. The results are compared with experimental data for polymethyl methacrylate, polyethylene, polycarbonate and polystyrene.

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(8)

• The temperature drops in glassy polymers while strained
• Mechanism of complicated volume deformation in polymers and its fractional time-based description
• Volume and enthalpy relaxation in glassy polymers
• Kinetics of volume recovery in amorphous polymers
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• WHY CONDUCTIVITY DECREASES WITH PRESSURE IN ION-DOPED POLYMERS
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• A discussion on volume change in the plastic phase

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