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The author describes all additive mappings \\(G:M_{n}(\\mathbb K)\\to M_{n}(\\mathbb K)\\) satisfying the condition \\(G(x)x=xG(x)\\) for all \\(x\\) from one of the following subsets of \\(M_{n}(\\mathbb K)\\): (i) the set of all singular \\(x\\in M_{n}(\\mathbb K)\\), and (ii) the set of all invertible \\(x\\in M_{n}(\\mathbb K)\\); in the second case the extra assumption \\(|\\mathbb K|>2\\) is made. In both cases such a \\(G\\) has the form \\(x\\mapsto\\lambda x + \\mu(x)\\), where \\(\\lambda\\) is a scalar multiple of the identity matrix and \\(\\mu\\) is an additive mapping of \\(M_{n}(\\mathbb K)\\) into its centre. An illustrative example shows that in (ii) the assumption on \\(|\\mathbb K|\\) must not be 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