Application of the quantum mechanical hyperviral theorems to even-power series potentials

DOI10.1007/BF02435943MaRDI QIDQ1380917zbMATH OpenFDO

Authors Th. E. Liolios, M. E. Grypeos

Publication date 23 July 1998

Published in International Journal of Theoretical Physics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1007/BF02435943

zbMATH Keywords

estimation of energy eigenvaluesquantum-mechanical hypervirial theoremradial Schrödinger equation

Mathematics Subject Classification ID

Particular ordinary differential operators (Dirac, one-dimensional Schrödinger, etc.) (34L40) Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05)

Review text

The radial Schrödinger equation with potential \[ V(r)=-c+w^{2} r^{2}+ \sum_{k=1}^{\infty} V_{k} \lambda^{k} r^{2k+2} \] is considered, where \(c\) and \(w\) are positive constants, \(V_{k}\) are constants, and \(\lambda\) is a small parameter. Using expansions in powers of \(\lambda\) and the quantum-mechanical hypervirial theorem [\textit{J. O. Hirschfelder}, J. Chem. Phys. 33, 1462-1466 (1960)], the authors evaluate the first few terms in the expansions of the energy eigenvalues and of the expectation values for the potential and kinetic energies.

Recommendations

• Algebraic and numerical manipulation of the even-power-series central potentials by means of the hypervirial theorems technique
• Eigenenergies of the r²+ lambda r²/(1+gr²) and 1/2(r²)-or+gr⁴/(1+g alpha r²) potentials obtained by the hypervirial method
• Approximate analytic expressions for expectation values and the ``uncertainty product for even-power-series central potentials using the HVT method
• Schrödinger equation solutions for the central field power potential energy. I: \(V(r) = V_{0}(r/a_{0})^{2{\nu}-2}\), \({\nu}{\geqslant}1\)

Cites work

• A note on the Schrodinger equation for the potential A exp(-x²)-l(l+1)/x²
• Canonical perturbation expansions to large order from classical hypervirial and Hellmann–Feynman theorems
• Eigenenergies of the r²+ lambda r²/(1+gr²) and 1/2(r²)-or+gr⁴/(1+g alpha r²) potentials obtained by the hypervirial method
• Forces in Molecules
• Hypervirial theorems
• On the Schrodinger equation for the gaussian potential -A exp(-λr²)
• On the Schrodinger equation for the interaction x²+λx²/(1+gx²)
• Propagation of Flames Supported by a Zeroeth-Order Chemical Reaction
• The eigenvalues of the Schrodinger equation for spherically symmetric states for various types of potentials in two, three and N dimensions, by using perturbative and non-perturbative methods
• The energy levels of the Schrodinger equation for various types of potentials using a renormalized method
• The perturbed three-dimensional oscillator

Cited in

(6)

• Algebraic and numerical manipulation of the even-power-series central potentials by means of the hypervirial theorems technique
• Use of the principle of minimal sensitivity, the hypervirial and Hellmann-Feynman theorems in 1/N expansion for the calculation of bound states energies
• Quantum information entropies for the -state Pöschl-Teller-type potential
• Approximate analytic expressions for expectation values and the ``uncertainty product for even-power-series central potentials using the HVT method
• Eigenenergies of the r²+ lambda r²/(1+gr²) and 1/2(r²)-or+gr⁴/(1+g alpha r²) potentials obtained by the hypervirial method
• The Jacobi eigenfunctions and the quantum mechanical hypervirial theorems method for bound-state problems

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