Finite-time fluctuation theorem for diffusion-influenced surface reactions

DOI10.1088/1742-5468/AAD7C2MaRDI QIDQ3303317zbMATH OpenOpenAlexFDO

Authors Raymond Kapral, P. Gaspard

Publication date 11 August 2020

Published in Journal of Statistical Mechanics: Theory and Experiment (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1806.03662

Mathematics Subject Classification ID

Stochastic methods (Fokker-Planck, Langevin, etc.) applied to problems in time-dependent statistical mechanics (82C31) Classical flows, reactions, etc. in chemistry (92E20)

Abstract: A finite-time fluctuation theorem is proved for the diffusion-influenced surface reaction A<->B in a domain with any geometry where the species A and B undergo diffusive transport between the reservoir and the catalytic surface. A corresponding finite-time thermodynamic force or affinity is associated with the symmetry of the fluctuation theorem. The time dependence of the affinity and the reaction rates characterizing the stochastic process can be expressed analytically in terms of the solution of deterministic diffusion equations with specific boundary conditions.

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Cited in

(8)

• Finite-time fluctuation theorem for diffusion-influenced surface reactions on spherical and Janus catalytic particles
• The stochastic motion of self-thermophoretic Janus particles
• A stochastic approach to surface reactions including energetic interactions: I. Theory
• Fluctuation theorem for birth–death or chemical master equations with time-dependent rates
• Diffusion-mediated surface reactions and stochastic resetting
• Counting statistics and microreversibility in stochastic models of transistors
• Statistics of dwell times in a reaction with randomly fluctuating rates
• Encounter-based reaction-subdiffusion model I: surface adsorption and the local time propagator

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