Finite-time fluctuation theorem for diffusion-influenced surface reactions on spherical and Janus catalytic particles

DOI10.1088/1742-5468/AAEDA1MaRDI QIDQ3303260zbMATH OpenOpenAlexWikidataFDO

Authors Patrick Grosfils, Mu-Jie Huang, Raymond Kapral, P. Gaspard

Publication date 11 August 2020

Published in Journal of Statistical Mechanics: Theory and Experiment (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1807.06553

Mathematics Subject Classification ID

Dynamics of random walks, random surfaces, lattice animals, etc. in time-dependent statistical mechanics (82C41) Classical flows, reactions, etc. in chemistry (92E20)

Abstract: A finite-time fluctuation theorem for the diffusion-influenced surface reaction A <=> B is investigated for spherical and Janus catalytic particles. The finite-time rates and thermodynamic force are analytically calculated by solving diffusion equations with the special boundary conditions of the finite-time fluctuation theorem. Theory is compared with numerical simulations carried out with two different methods: a random walk algorithm and multiparticle collision dynamics.

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Cites work

• A Gallavotti-Cohen-type symmetry in the large deviation functional for stochastic dynamics
• Current fluctuations in the one-dimensional symmetric exclusion process with open boundaries
• Extension of Onsager's Reciprocity to Large Fields and the Chaotic Hypothesis
• Finite-time fluctuation theorem for diffusion-influenced surface reactions
• Fluctuation theorem for stochastic dynamics
• Partially Reflected Diffusion
• Probability of second law violations in shearing steady states

Cited in

(2)

• Finite-time fluctuation theorem for diffusion-influenced surface reactions
• Counting statistics and microreversibility in stochastic models of transistors

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