Interface tension in a binary system with curved boundary

DOI10.3103/S1062873807050395MaRDI QIDQ735785zbMATH OpenFDO

Authors M. A. Shebzukhova, A. A. Shebzukhov

Publication date 26 October 2009

Published in Bulletin of the Russian Academy of Sciences: Physics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.3103/S1062873807050395

zbMATH Keywords

classical thermodynamicscurved boundariesinterface problemsinterface tension

Mathematics Subject Classification ID

Classical and relativistic thermodynamics (80A10) Boundary element methods applied to problems in thermodynamics and heat transfer (80M15) Classical equilibrium statistical mechanics (general) (82B05) Phase transitions (general) in equilibrium statistical mechanics (82B26)

Review text

The article considers the interface tension in an isothermal binary system consisting of a dispersed \(\alpha\) phase -- a spherical particle -- and a dispersing medium \(\beta\). The equation of interface tension is derived from the thermodynamic equilibrium conditions using expressions of the molar Gibbs potentials in the bulk \(\alpha\)-phases and the interface layer. In the model, the partial derivatives of the bulk phases are taken at constant pressure. At the interface layer, the derivatives are found for constant pressure and constant interface tension. In the case of a one-component systems, the well-known expressions for the size dependence of surface tension, previously obtained by other researchers (in particular, the Tolman formula), follow from the equation derived.

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