scientific article; zbMATH DE number 2035956

MaRDI QIDQ4445406zbMATH OpenFDO

Authors R. V. Gol'dshtein, M. E. Sarychev

Publication date 2 February 2004

zbMATH Keywords

admixtureGibbs equationgrain boundarysurface tension

Mathematics Subject Classification ID

Interface problems; diffusion-limited aggregation arising in equilibrium statistical mechanics (82B24) Statistical mechanics of crystals (82D25)

Review text

The thermodynamic Gibbs equation \[ d\gamma_{12} = -\Gamma_1^{(0)}d\mu_1^{(0)} - \Gamma_1d\mu_1 - \Gamma_2^{(0)}d\mu_2^{(0)} - \Gamma_2d\mu_2 \] is considered, where \(d\gamma_{12}\) is change of surface tension, \(d\mu_i^{(0)}\) and \(d\mu_i\) are changes of chemical potentials of matrix and of admixture in i-th material \(i = 1,2\). \(\Gamma_i^{(0)}\) and \(\Gamma_i\) are specific numbers of atoms of matrix and of admixture per the grain boundary surface.

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Cited in

(4)

• Extension of Gibbs-Duhem equation including influences of external fields
• On the Gibbs adsorption equation and diffuse interface models
• The Tolman parameter, self-absorption, and surface tension on flat and curved surfaces of liquid metals
• Interface tension in a binary system with curved boundary

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