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scientific article; zbMATH DE number 2035956
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scientific article; zbMATH DE number 2035956 |
Statements
2 February 2004
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surface tension
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grain boundary
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admixture
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Gibbs equation
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0.7506541609764099
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0.7236791849136353
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0.6967043876647949
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0.6965327262878418
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The thermodynamic Gibbs equation \[ d\gamma_{12} = -\Gamma_1^{(0)}d\mu_1^{(0)} - \Gamma_1d\mu_1 - \Gamma_2^{(0)}d\mu_2^{(0)} - \Gamma_2d\mu_2 \] is considered, where \(d\gamma_{12}\) is change of surface tension, \(d\mu_i^{(0)}\) and \(d\mu_i\) are changes of chemical potentials of matrix and of admixture in i-th material \(i = 1,2\). \(\Gamma_i^{(0)}\) and \(\Gamma_i\) are specific numbers of atoms of matrix and of admixture per the grain boundary surface.
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