Large deviation analysis of a droplet model having a Poisson equilibrium distribution

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Abstract: One of the main contributions of this paper is to illustrate how large deviation theory can be used to determine the equilibrium distribution of a basic droplet model that underlies a number of important models in material science and statistical mechanics. The model is simply defined. K distinguishable particles are placed at random onto the N sites of a lattice, where the ratio K/N, the average number of particles per site, equals a constant cin(1,infty). We focus on configurations for which each site is occupied by at least one particle. The main result is the large deviation principle (LDP), in the limit where Kightarrowinfty and Nightarrowinfty with K/N=c, for a sequence of random, number-density measures, which are the empirical measures of dependent random variables that count the droplet sizes. The rate function in the LDP is the relative entropy R(heta|ho∗), where heta is a possible asymptotic configuration of the number-density measures and ho∗ is a Poisson distribution restricted to the set of positive integers. This LDP reveals that ho∗ is the equilibrium distribution of the number-density measures, which in turn implies that ho∗ is the equilibrium distribution of the random variables that count the droplet sizes. We derive the LDP via a local large deviation estimate of the probability that the number-density measures equal heta for any probability measure heta in the range of these random measures.


Summary: In this paper, we use large deviation theory to determine the equilibrium distribution of a basic droplet model that underlies a number of important models in material science and statistical mechanics. Given \(b \in \mathbb{N}\) and \(c > b\), \(K\) distinguishable particles are placed, each with equal probability \(1 / N\), onto the \(N\) sites of a lattice, where \(K / N\) equals \(c\). We focus on configurations for which each site is occupied by a minimum of \(b\) particles. The main result is the large deviation principle (LDP), in the limit \(K \to \infty\) and \(N \to \infty\) with \(K / N = c\), for a sequence of random, number-density measures, which are the empirical measures of dependent random variables that count the droplet sizes. The rate function in the LDP is the relative entropy \(R(\theta \mid \rho^\ast)\), where \(\theta\) is a possible asymptotic configuration of the number-density measures and \(\rho^\ast\) is a Poisson distribution with mean \(c\), restricted to the set of positive integers \(n\) satisfying \(n \geq b\). This LDP implies that \(\rho^\ast\) is the equilibrium distribution of the number-density measures, which in turn implies that \(\rho^\ast\) is the equilibrium distribution of the random variables that count the droplet sizes.



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