Kiselev isotherm model

Community: MathModDB

deterministic model

dimensional model

mathematical model

nonlinear model

static model

Available identifiers

MaRDI QIDQ6820970

adsorption model for localized monolayer with complex formation, named after Andrey Kiselyov

Description

The Kiselev isotherm model describes adsorption occurring in a localized monomolecular layer, where adsorbate molecules may form surface complexes with one another. Unlike the Langmuir model, Kiselev explicitly includes a complex-formation parameter that accounts for associations between adsorbed molecules at neighboring sites. This allows the model to represent cooperative or associative adsorption behavior on heterogeneous or interacting surfaces. It is used primarily to interpret adsorption on solids where pairwise interactions or dimer formation occurs. Applications include surface chemistry, catalysis, and environmental adsorption processes such as chemical wastewater treatment.

List of contained entities

Kiselev equation	$k_1{C}_e=\frac{\theta }{(1-\theta )(1+k_n\theta )}$
	$C_e$ represents solute concentration (equilibrium)
	$\theta$ represents fractional surface coverage
	$k_1$ represents Kiselev equilibrium constant
	$k$ represents complex formation constant

List of computational tasks

linear parameter estimation (Kiselev model)

nonlinear parameter estimation (Kiselev model)

Described at:

Monolayer and multilayer adsorption isotherm models for sorption from aqueous media

(review)

Further items linking to Kiselev isotherm model

Item	Property
chemical wastewater treatment	modelled by

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