The fast-sorption and fast-surface-reaction limit of a heterogeneous catalysis model

DOI10.3934/DCDSS.2020406zbMATH Open1459.35243arXiv1911.13030OpenAlexW3043457664MaRDI QIDQ1995430FDOQ1995430

Dieter Bothe, Björn Augner

Publication date: 23 February 2021

Published in: Discrete and Continuous Dynamical Systems. Series S (Search for Journal in Brave)

Abstract: Every mathematical model describing physical phenomena is an approximation to model reality, hence has its limitations. Depending on characteristic values of the variables in the model, different aspects of the model and, e.g., thermodynamic mechanisms have to be emphasised, or may be neglected in a reduced limit model. Within this paper, a heterogeneous catalysis system will be considered consisting of a bulk phase $Omega$ (chemical reactor) and an active surface $Sigma=partialOmega$ (catalytic surface), between which chemical substances are exchanged via adsorption (transport of mass from the bulk boundary layer adjacent to the surface, leading to surface-accumulation by a transformation into an adsorbed form) and desorption (vice versa). Quite typically, as is the purpose of catalysis, chemical reactions on the surface occur several orders of magnitude faster than, say, chemical reactions within the bulk, and sorption processes are often quite fast as well. Starting from the non-dimensional version, different limit models, especially for fast surface chemistry and fast sorption at the surface, are considered. For a particular model problem, questions of local-in-time existence of strong and classical solutions, positivity of solutions and blow-up criteria for global existence are addressed.

Full work available at URL: https://arxiv.org/abs/1911.13030

zbMATH Keywords

blow-upquasilinear PDEpositivitysurface diffusionreaction diffusion systemsheterogeneous catalysisdimension analysissorption\(L_p\)-maximal regularitysurface chemistry

Mathematics Subject Classification ID

Quasilinear parabolic equations (35K59) Initial-boundary value problems for second-order parabolic systems (35K51) Reaction-diffusion equations (35K57) Chemical kinetics in thermodynamics and heat transfer (80A30) Classical flows, reactions, etc. in chemistry (92E20)

Cites Work

• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Optimal \(L^{p}\)- \(L^{q}\)-estimates for parabolic boundary value problems with inhomogeneous data
• ℛ-boundedness, Fourier multipliers and problems of elliptic and parabolic type
• Geometric theory of semilinear parabolic equations
• Global existence for semilinear parabolic systems.
• Dynamic theory of quasilinear parabolic equations—I. Abstract evolution equations
• Analytic semigroups and optimal regularity in parabolic problems
• Global existence in reaction-diffusion systems with control of mass: a survey
• Global solutions of reaction-diffusion systems
• Dynamic theory of quasilinear parabolic equations. II: Reaction-diffusion systems
• Dynamic theory of quasilinear parabolic systems. III: Global existence
• General parabolic mixed order systems in \(L_p\) and applications
• The \(H^\infty\)-calculus and sums of closed operators
• Maximal \(L_p\)-regularity of parabolic problems with boundary dynamics of relaxation type
• Parabolic evolution equations and nonlinear boundary conditions
• Weak solutions and supersolutions in \(L^1\) for reaction-diffusion systems
• Improved Duality Estimates and Applications to Reaction-Diffusion Equations
• Global existence for a class of reaction-diffusion systems with mass action kinetics and concentration-dependent diffusivities
• Global Existence for Quadratic Systems of Reaction-Diffusion
• Exponential decay toward equilibrium via entropy methods for reaction-diffusion equations
• Dual semigroups and second order linear elliptic boundary value problems
• Entropy methods for reaction-diffusion equations: Slowly growing a-priori bounds
• Blowup in Reaction-Diffusion Systems with Dissipation Of Mass
• Global strong solutions for a class of heterogeneous catalysis models
• Continuum thermodynamics of chemically reacting fluid mixtures
• Quasi-steady-state approximation for a reaction-diffusion system with fast intermediate
• The instantaneous limit for reaction-diffusion systems with a fast irreversible reaction
• Stable and unstable manifolds for quasilinear parabolic problems with fully nonlinear dynamical boundary conditions
• On the Maxwell-Stefan Approach to Multicomponent Diffusion
• Reaction-diffusion systems of Maxwell-Stefan type with reversible mass-action kinetics
• Trend to Equilibrium for Reaction-Diffusion Systems Arising from Complex Balanced Chemical Reaction Networks
• Interpolation Theory
• The instantaneous limit of a reaction-diffusion system
• Linear and Quasilinear Parabolic Problems
• A continuum model of heterogeneous catalysis: thermodynamic framework for multicomponent bulk and surface phenomena coupled by sorption
• Analysis of Cross-Diffusion Systems for Fluid Mixtures Driven by a Pressure Gradient

Cited In (6)

• Analysis of bulk-surface reaction-sorption-diffusion systems with Langmuir-type adsorption
• Maximal mixed parabolic–hyperbolic regularity for the full equations of multicomponent fluid dynamics
• A continuum model of heterogeneous catalysis: thermodynamic framework for multicomponent bulk and surface phenomena coupled by sorption
• Analysis of some heterogeneous catalysis models with fast sorption and fast surface chemistry
• Product desorption rate influence on catalytic reactivity of spatially inhomogeneous surfaces
• \(L_p\)-maximal regularity for parabolic and elliptic boundary value problems with boundary conditions of mixed differentiability orders

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