The fast-sorption and fast-surface-reaction limit of a heterogeneous catalysis model

DOI10.3934/DCDSS.2020406zbMATH Open1459.35243arXiv1911.13030OpenAlexW3043457664MaRDI QIDQ1995430FDOQ1995430

Authors: Björn Augner, Dieter Bothe 

Publication date: 23 February 2021

Published in: Discrete and Continuous Dynamical Systems. Series S (Search for Journal in Brave)

Abstract: Every mathematical model describing physical phenomena is an approximation to model reality, hence has its limitations. Depending on characteristic values of the variables in the model, different aspects of the model and, e.g., thermodynamic mechanisms have to be emphasised, or may be neglected in a reduced limit model. Within this paper, a heterogeneous catalysis system will be considered consisting of a bulk phase $Omega$ (chemical reactor) and an active surface $Sigma=partialOmega$ (catalytic surface), between which chemical substances are exchanged via adsorption (transport of mass from the bulk boundary layer adjacent to the surface, leading to surface-accumulation by a transformation into an adsorbed form) and desorption (vice versa). Quite typically, as is the purpose of catalysis, chemical reactions on the surface occur several orders of magnitude faster than, say, chemical reactions within the bulk, and sorption processes are often quite fast as well. Starting from the non-dimensional version, different limit models, especially for fast surface chemistry and fast sorption at the surface, are considered. For a particular model problem, questions of local-in-time existence of strong and classical solutions, positivity of solutions and blow-up criteria for global existence are addressed.

Full work available at URL: https://arxiv.org/abs/1911.13030

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zbMATH Keywords

blow-upquasilinear PDEpositivitysurface diffusionreaction diffusion systemsheterogeneous catalysisdimension analysissorption\(L_p\)-maximal regularitysurface chemistry

Mathematics Subject Classification ID

Quasilinear parabolic equations (35K59) Initial-boundary value problems for second-order parabolic systems (35K51) Reaction-diffusion equations (35K57) Chemical kinetics in thermodynamics and heat transfer (80A30) Classical flows, reactions, etc. in chemistry (92E20)

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Cited In (8)

• Analysis of bulk-surface reaction-sorption-diffusion systems with Langmuir-type adsorption
• Maximal mixed parabolic–hyperbolic regularity for the full equations of multicomponent fluid dynamics
• Chemical Kinetics on Surfaces: A Singular Limit of a Reaction‐Diffusion System
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