Classical and quantum controllability of a rotating asymmetric molecule

DOI10.1007/S00245-022-09821-YMaRDI QIDQ2115122zbMATH OpenOpenAlexFDO

Authors Eugenio Pozzoli

Publication date 15 March 2022

Published in Applied Mathematics and Optimization (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/2108.01943

zbMATH Keywords

bilinear control systemsEuler equationsquantum controlrotational dynamicsasymmetric top moleculeSchrödinger equation

Mathematics Subject Classification ID

Schrödinger operator, Schrödinger equation (35J10) Controllability (93B05) Molecular physics (81V55) Control/observation systems governed by partial differential equations (93C20) Quantum control (81Q93)

Abstract: We study both the classical and quantum rotational dynamics of an asymmetric top molecule, controlled through three orthogonal electric fields that interact with its dipole moment. The main difficulties in studying the controllability of these infinite-dimensional quantum systems are the presence of severe spectral degeneracies in the drift Hamiltonian and the nonsolvability of the stationary free Schr"odinger equation, which lead us to apply a perturbative Lie algebraic approach. In this paper we show that, while the classical equations given by the Hamiltonian system on $mSO(3)imesmathbb{R}^3$ are controllable for all values of the rotational constants and all dipole configurations, the Sch"odinger equation for the quantum evolution on $L^2(mSO(3))$ is approximately controllable for almost all values of the rotational constants if and only if the dipole is not parallel to any of the principal axes of inertia of the asymmetric rigid body.

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Cited in

(8)

• Classical and quantum controllability of a rotating symmetric molecule
• Control of classical regime molecular objectives -- applications of tracking and variations on the theme
• Multi-polarization quantum control of rotational motion through dipole coupling
• External constraints on optimal control strategies in molecular orientation and photofragmentation: role of zero-area fields
• Lie algebra for rotational subsystems of a driven asymmetric top
• Signatures of physical constraints in rotating rigid bodies
• CLASSICAL MECHANICS OF DIPOLAR ASYMMETRIC TOP MOLECULES IN COLLINEAR STATIC ELECTRIC AND NONRESONANT LINEARLY POLARIZED LASER FIELDS: ENERGY-MOMENTUM DIAGRAMS, BIFURCATIONS AND ACCESSIBLE CONFIGURATION SPACE
• Small-time bilinear control of Schrödinger equations with application to rotating linear molecules

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