The behavior of a many-particle electrode in a lithium-ion battery

DOI10.1016/J.PHYSD.2011.02.011MaRDI QIDQ2276144zbMATH OpenOpenAlexFDO

Authors Clemens Guhlke, Robert Huth, Wolfgang Dreyer

Publication date 1 August 2011

Published in Physica D (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1016/j.physd.2011.02.011

zbMATH Keywords

chemical potentialhysteresislithium-ion batterymany-particle systemphase transitionthermodynamic

Mathematics Subject Classification ID

Thermodynamics in solid mechanics (74A15) Molecular, statistical, and kinetic theories in solid mechanics (74A25) Stefan problems, phase changes, etc. (80A22) Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs arising in equilibrium statistical mechanics (82B20) Continuum models (systems of particles, etc.) arising in equilibrium statistical mechanics (82B21) Phase transitions (general) in equilibrium statistical mechanics (82B26)

Review text

The authors consider a rechargeable lithium-ion battery that uses a many-particle \(FePO_4\) electrode to reversibly store lithium atoms and study in detail a many-particle model for the electrode. The model is capable to describe a kind of phase transition where each individual particle of the electrode is homogeneous. This phenomenon is due to the non-monotone relation between the chemical potential and the lithium mole fraction of a single particle.

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Cites work

• scientific article; zbMATH DE number 4016286 (Why is no real title available?)
• Hysteresis and phase transition in many-particle storage systems
• On the modelling of semi-insulating GaAs including surface tension and bulk stresses
• Phase transition in a rechargeable lithium battery
• Rate-independent hysteresis in a bi-stable chain.
• Thermodynamics

Cited in

(14)

• Stochastic many-particle model for LFP electrodes
• Mathematical modeling of hysteresis in porous electrodes
• A thermo-chemo-mechanically coupled model for cathode particles in lithium-ion batteries
• Phase-field study of electrochemical reactions at exterior and interior interfaces in Li-ion battery electrode particles
• A statistical mechanical study of current spikes due to phase transitions at electrode-electrolyte interfaces
• Deterministic and stochastic analysis of the lithiation/delithiation dynamics of a cathode nanoparticle
• Phase transition in a rechargeable lithium battery
• Hysteresis and phase transition in many-particle storage systems
• Hysteresis and phase transition in many-particle storage systems
• A modelling framework for efficient reduced order simulations of parametrised lithium-ion battery cells
• Bifurcations of clusters and collective oscillations in networks of bistable units
• Homogenization of a porous intercalation electrode with phase separation
• Modeling elastically-coupled diffusive phase growth in two-phase binary solids
• Effect of cycling rate, particle size and transport properties on lithium-ion cathode performance

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