Thermodynamic substantiation of heuristic expressions for the heat of transition of first order phase transformations

DOI10.1134/S1028335807010041MaRDI QIDQ2425576zbMATH OpenFDO

Authors A. A. Sobko

Publication date 6 May 2008

Published in Doklady Physics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1134/S1028335807010041

zbMATH Keywords

crystalsfirst order phase transformationthermodynamics

Mathematics Subject Classification ID

Phase transitions (general) in equilibrium statistical mechanics (82B26) Statistical mechanics of crystals (82D25)

Review text

On the basis of the first principle of thermodynamics the author presents an explicit expression for the heat release of the first order phase tranformations. Calculations are performed for heat release at melting of fcc, bcc, and hcp-lattice crystals and evaporation.

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(3)

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• Phase transitions of the first kind as radiation processes
• Relation between the thermodynamic parameters at the critical point and determination of the effective volumes of molecules

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