Generalisation of the Eyring-Kramers transition rate formula to irreversible diffusion processes
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Publication:730134
Abstract: In the small noise regime, the average transition time between metastable states of a reversible diffusion process is described at the logarithmic scale by Arrhenius' law. The Eyring-Kramers formula classically provides a subexponential prefactor to this large deviation estimate. For irreversible diffusion processes, the equivalent of Arrhenius' law is given by the Freidlin-Wentzell theory. In this paper, we compute the associated prefactor and thereby generalise the Eyring-Kramers formula to irreversible diffusion processes. In our formula, the role of the potential is played by Freidlin-Wentzell's quasipotential, and a correction depending on the non-Gibbsianness of the system along the instanton is highlighted. Our analysis relies on a WKB analysis of the quasistationary distribution of the process in metastable regions, and on a probabilistic study of the process in the neighbourhood of saddle-points of the quasipotential.
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Cites work
- scientific article; zbMATH DE number 1158743 (Why is no real title available?)
- scientific article; zbMATH DE number 2208078 (Why is no real title available?)
- A Dirichlet principle for non reversible Markov chains and some recurrence theorems
- A Ray Method for the Asymptotic Solution of the Diffusion Equation
- Accelerating Gaussian diffusions
- Accelerating diffusions
- An Eyring-Kramers law for the stochastic Allen-Cahn equation in dimension two
- Brownian motion in a field of force and the diffusion model of chemical reactions
- Free energy computations. A mathematical perspective
- Kramers law: validity, derivations and generalisations
- Limiting Exit Location Distributions in the Stochastic Exit Problem
- Metastability for a non-reversible dynamics: the evolution of the condensate in totally asymmetric zero range processes
- Metastability in reversible diffusion processes. I: Sharp asymptotics for capacities and exit times
- Metastability of Nonreversible Random Walks in a Potential Field and the Eyring‐Kramers Transition Rate Formula
- Noise-induced phase slips, log-periodic oscillations, and the Gumbel distribution
- Non-classical large deviations for a noisy system with non-isolated attractors
- Observable and hidden singular features of large fluctuations in nonequilibrium systems
- On the noise-induced passage through an unstable periodic orbit. I: Two-level model
- On the noise-induced passage through an unstable periodic orbit. II: General case
- On the weak-noise limit of Fokker-Planck models
- Optimal non-reversible linear drift for the convergence to equilibrium of a diffusion
- Persistence of Dynamical Systems under Random Perturbations
- Perturbative calculation of quasi-potential in non-equilibrium diffusions: a mean-field example
- Poincaré and logarithmic Sobolev inequalities by decomposition of the energy landscape
- Random Perturbations of Dynamical Systems
- Sharp asymptotics of metastable transition times for one dimensional SPDEs
- Sharp estimates for metastable lifetimes in parabolic SPDEs: Kramers law and beyond
- Singularities in large deviation functions
- Small noise spectral gap asymptotics for a large system of nonlinear diffusions
- Some regularity results on the Ventcel-Freidlin quasi-potential function
- Stability of regime-switching stochastic differential equations
- Testing transition state theory on Kac-Zwanzig model
- The Exit Problem for Randomly Perturbed Dynamical Systems
- The Exit Problem: A New Approach to Diffusion Across Potential Barriers
- The Eyring-Kramers law for Markovian jump processes with symmetries
- The Eyring-Kramers law for potentials with nonquadratic saddles
- Theory and applications of stochastic processes. An analytical approach
- Uniform estimates for metastable transition times in a coupled bistable system
Cited in
(48)- An Eyring-Kramers law for slowly oscillating bistable diffusions
- Application of adaptive multilevel splitting to high-dimensional dynamical systems
- The exit from a metastable state: concentration of the exit point distribution on the low energy saddle points. II
- Computing transition rates for the 1-D stochastic Ginzburg-Landau-Allen-Cahn equation for finite-amplitude noise with a rare event algorithm
- Collapse of transitional wall turbulence captured using a rare events algorithm
- Generalized mean relaxation time formalism for activated rate processes without manifest detailed balance
- Metastable transitions in inertial Langevin systems: what can be different from the overdamped case?
- Spectral theory for random Poincaré maps
- Ergodicity of the infinite swapping algorithm at low temperature
- An ordered line integral method for computing the quasi-potential in the case of variable anisotropic diffusion
- Driven interfaces: from flow to creep through model reduction
- Irreversible reactions and diffusive escape: stationary properties
- Non-reversible metastable diffusions with Gibbs invariant measure. I: Eyring-Kramers formula
- Symmetries and zero modes in sample path large deviations
- An efficient jet marcher for computing the quasipotential for 2D SDEs. Enhancing accuracy and efficiency of quasipotential solvers
- Sharp spectral asymptotics for nonreversible metastable diffusion processes
- Exit time and principal eigenvalue of non-reversible elliptic diffusions
- Large-deviation theory for a Brownian particle on a ring: a WKB approach
- An efficient algorithm to estimate the potential barrier height from noise-induced escape time data
- Approximate Optimal Controls via Instanton Expansion for Low Temperature Free Energy Computation
- Computing the quasipotential for nongradient SDEs in 3D
- Thermalisation for small random perturbations of dynamical systems
- Sharp asymptotic estimates for expectations, probabilities, and mean first passage times in stochastic systems with small noise
- Computing the quasipotential for highly dissipative and chaotic SDEs an application to stochastic Lorenz'63
- Sharp asymptotics of the first exit point density
- Kramers law: validity, derivations and generalisations
- Non-reversible metastable diffusions with Gibbs invariant measure. II: Markov chain convergence
- Simple generalization of Kramers theory to finite barrier height in spatial diffusion regime
- The Eyring-Kramers law for potentials with nonquadratic saddles
- Efficient characterisation of large deviations using population dynamics
- Hyperbolic periodic orbits in nongradient systems and small-noise-induced metastable transitions
- Metastable Markov chains
- Metastability of one-dimensional, non-reversible diffusions with periodic boundary conditions
- Parametric resonance for enhancing the rate of metastable transition
- A graph-algorithmic approach for the study of metastability in Markov chains
- The Eyring-Kramers law for Markovian jump processes with symmetries
- Reduction of a stochastic model of gene expression: Lagrangian dynamics gives access to basins of attraction as cell types and metastabilty
- Geometric characterization of the Eyring-Kramers formula
- Metastability of non-reversible, mean-field Potts model with three spins
- Quasi-stationary distribution for the Langevin process in cylindrical domains. I: Existence, uniqueness and long-time convergence
- Computing return times or return periods with rare event algorithms
- Path integral derivation and numerical computation of large deviation prefactors for non-equilibrium dynamics through matrix Riccati equations
- A kinetic Monte Carlo approach for simulating cascading transmission line failure
- Scaling limit of small random perturbation of dynamical systems
- Dirichlet's and Thomson's principles for non-selfadjoint elliptic operators with application to non-reversible metastable diffusion processes
- Global stability properties of the climate: melancholia states, invariant measures, and phase transitions
- Stochastic model for barrier crossings and fluctuations in local timescale
- Metastability of Nonreversible Random Walks in a Potential Field and the Eyring‐Kramers Transition Rate Formula
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