The time-dependent Born-Oppenheimer approximation
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Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Perturbation theories for operators and differential equations in quantum theory (81Q15) Differential geometric methods, including holonomy, Berry and Hannay phases, Aharonov-Bohm effect, etc. in quantum theory (81Q70)
Abstract: We explain why the conventional argument for deriving the time-dependent Born-Oppenheimer approximation is incomplete and review recent mathematical results, which clarify the situation and at the same time provide a systematic scheme for higher order corrections. We also present a new elementary derivation of the correct second-order time-dependent Born-Oppenheimer approximation and discuss as applications the dynamics near a conical intersection of potential surfaces and reactive scattering.
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Cites work
- A general reduction scheme for the time-dependent Born-Oppenheimer approximation.
- A time dependent Born-Oppenheimer approximation
- A time-dependent Born-Oppenheimer approximation with exponentially small error estimates.
- Adiabatic decoupling and time-dependent Born-Oppenheimer theory
- Adiabatic perturbation theory in quantum dynamics
- Geometry of the transport equation in multicomponent WKB approximations
- High order corrections to the time-dependent Born-Oppenheimer approximation. I: Smooth potentials
- scientific article; zbMATH DE number 458936 (Why is no real title available?)
- scientific article; zbMATH DE number 1330837 (Why is no real title available?)
- scientific article; zbMATH DE number 1911253 (Why is no real title available?)
- Mesures semi-classiques et croisement de modes
- Molecular propagation through electron energy level crossings
- On the Born-Oppenheimer expansion for polyatomic molecules
- Propagation through conical crossings: An asymptotic semigroup
- Reduction Scheme for Semiclassical Operator-Valued Schrödinger Type Equation and Application to Scattering
- Scattering amplitude for dirac operators
- Semiclassical limit for multistate Klein–Gordon systems: almost invariant subspaces, and scattering theory
- Wigner measures and codimension two crossings
Cited in
(27)- A general reduction scheme for the time-dependent Born-Oppenheimer approximation.
- WavePacket: a Matlab package for numerical quantum dynamics. I: Closed quantum systems and discrete variable representations
- Effective potentials generated by field interaction in the quasi-classical limit
- Canonical quantum observables for molecular systems approximated by ab initio molecular dynamics
- Weyl formulae for the Robin Laplacian in the semiclassical limit
- The adiabatic limit of the connection Laplacian
- Effective Hamiltonians for constrained quantum systems
- Born-Oppenheimer approximation for a singular system
- Coherent states, quantum gravity, and the Born-Oppenheimer approximation. I. General considerations
- Adiabatic approximation for a two-level atom in a light beam
- scientific article; zbMATH DE number 509273 (Why is no real title available?)
- Approximate controllability of the Jaynes-Cummings dynamics
- Effective light dynamics in perturbed photonic crystals
- Introduction to first-principle simulation of molecular systems
- Frozen Gaussian approximation with surface hopping for mixed quantum-classical dynamics: a mathematical justification of fewest switches surface hopping algorithms
- On the mathematical treatment of the Born-Oppenheimer approximation
- Long‐Range Behavior of the van der Waals Force
- Differential equations of quantum mechanics
- A calculus for magnetic pseudodifferential super operators
- Adiabatic decoupling and time-dependent Born-Oppenheimer theory
- A time-dependent Born-Oppenheimer approximation with exponentially small error estimates.
- A Born-Oppenheimer expansion in a neighborhood of a Renner-Teller intersection
- Quantum transport in crystals: Effective mass theorem and k\(\cdot\)p Hamiltonians
- Numerical test of Born-Oppenheimer approximation in chaotic systems
- Spontaneous decay of resonant energy levels for molecules with moving nuclei
- A proof of \({\mathfrak{L}}^2\)-boundedness for magnetic pseudodifferential super operators via matrix representations with respect to Parseval frames
- Effective dynamics for particles coupled to a quantized scalar field
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