Models and applications

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The author gives a survey of different models of growth (the ballistic growth model, the diffusion-limited aggregation model, the cluster-cluster aggregation model) and then discusses their properties obtained by computer simulations or analytical calculations. The ballistic growth is proved not to be fractal in the usual sense: the bulk density of ballistic aggregate grown in the deposition geometry achieves a constant value. Nevertheless the ballistic aggregation surface has scaling properties. The surface roughness \(\sigma\) is expressed asymptotically in terms of the deposition mean height \(H\) and the width \(L\) of the \((d-1)\)-dimensional substrate in such a way: \[ \sigma =L^{\alpha}, H >> L^z ; \;=H^{\beta}, H << L^z. \] Here \(\alpha, \beta, z\) are scaling exponents which satisfy the following equalities: \(\alpha=\beta z\), \(\alpha + z = 2\). For the trivial case of uncoupled ballistic growth \(\alpha\) is undefined, \(\beta\) = 1/2; in two dimensions \(\alpha = 1/2\), \(\beta = 1/3\) ; in three dimensions \(\alpha = 0.35\), \(\beta = 0.21\). The Kardar-Parisi-Zhang equation (1986) is shown to describe ballistic growth in continuous limit. The diffusion-limited aggregate is proved to be a self-similar fractal. The fractal dimension \(D\) is defined by the equality \(D = \frac{\ln\rho}{\ln M}\), where \(\rho\) is the mean radius and \(M\) the mass of the cluster. The dependence \(D(d)\) of the fractal dimension \(D\) on the physical space dimension \(d\) has the following values: \(D(2) = 1.7\), \(D(3) = 2.5\). A fundamental reason for the fractal shape of the diffusion-limited cluster is afflicted with a Mullins-Sekerka growth instability (1957). It appears that in order to stabilize the diffusive growth we need some kind of anisotropy. The author applies these results to the electrochemical deposition process. The cluster-cluster aggregation model appears to belong to another universality class than previous ones. The fractal dimensions for cluster-cluster aggregates are \(D(2) = 1.43\), \(D(3) = 1.75\). The author has appended to the paper a program for the construction of diffusion-limited aggregates and a list of problems. For the entire collection see [Zbl 0974.00042].











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