Towards a nonequilibrium thermodynamics: A Self-contained macroscopic description of driven diffusive systems
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Abstract: In this paper we present a self-contained macroscopic description of diffusive systems interacting with boundary reservoirs and under the action of external fields. The approach is based on simple postulates which are suggested by a wide class of microscopic stochastic models where they are satisfied. The description however does not refer in any way to an underlying microscopic dynamics: the only input required are transport coefficients as functions of thermodynamic variables, which are experimentally accessible. The basic postulates are local equilibrium which allows a hydrodynamic description of the evolution, the Einstein relation among the transport coefficients, and a variational principle defining the out of equilibrium free energy. Associated to the variational principle there is a Hamilton-Jacobi equation satisfied by the free energy, very useful for concrete calculations. Correlations over a macroscopic scale are, in our scheme, a generic property of nonequilibrium states. Correlation functions of any order can be calculated from the free energy functional which is generically a non local functional of thermodynamic variables. Special attention is given to the notion of equilibrium state from the standpoint of nonequilibrium.
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Cited in
(46)- Hydrodynamics and fluctuations outside of local equilibrium: driven diffusive systems.
- Geometrical excess entropy production in nonequilibrium quantum systems
- Eikonal solutions for moment hierarchies of chemical reaction networks in the limits of large particle number
- Large deviations of the current in stochastic collisional dynamics
- Onsager coefficients in a coupled-transport model displaying a condensation transition
- Tagged particle in single-file diffusion
- Thermodynamics of nonequilibrium driven diffusive systems in mild contact with boundary reservoirs
- Time evolution in macroscopic systems. III: Selected applications
- Absence of dissipation in trajectory ensembles biased by currents
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- Entropy and nonlinear nonequilibrium thermodynamic relation for heat conducting steady states
- Void formation in diffusive lattice gases
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- Nonequilibrium thermodynamics of the first and second kind: averages and fluctuations
- Totally asymmetric limit for models of heat conduction
- Current fluctuations in an interacting active lattice gas
- The information geometry of two-field functional integrals
- From fluctuations in hydrodynamics to nonequilibrium thermodynamics
- A diffusive system driven by a battery or by a smoothly varying field
- Externally driven macroscopic systems: dynamics versus thermodynamics
- Weak coupling limits in a stochastic model of heat conduction
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- Current fluctuations in one dimensional diffusive systems with a step initial density profile
- Correlations of the density and of the current in non-equilibrium diffusive systems
- Large deviations in stochastic heat-conduction processes provide a gradient-flow structure for heat conduction
- Singularities in large deviation functions
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